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The air–sea exchange and oceanic cycling of greenhouse gases (GHG), including carbon dioxide (CO2), nitrous oxide (N2O), methane (CH4), carbon monoxide (CO), and nitrogen oxides (NOx = NO + NO2), are fundamental in controlling the evolution of the Earth’s atmospheric chemistry and climate. Significant advances have been made over the last 10 years in understanding, instrumentation and methods, as well as deciphering the production and consumption pathways of GHG in the upper ocean (including the surface and subsurface ocean down to approximately 1000 m). The global ocean under current conditions is now well established as a major sink for CO2, a major source for N2O and a minor source for both CH4 and CO. The importance of the ocean as a sink or source of NOx is largely unknown so far. There are still considerable uncertainties about the processes and their major drivers controlling the distributions of N2O, CH4, CO, and NOx in the upper ocean. Without having a fundamental understanding of oceanic GHG production and consumption pathways, our knowledge about the effects of ongoing major oceanic changes—warming, acidification, deoxygenation, and eutrophication—on the oceanic cycling and air–sea exchange of GHG remains rudimentary at best. We suggest that only through a comprehensive, coordinated, and interdisciplinary approach that includes data collection by global observation networks as well as joint process studies can the necessary data be generated to (1) identify the relevant microbial and phytoplankton communities, (2) quantify the rates of ocean GHG production and consumption pathways, (3) comprehend their major drivers, and (4) decipher economic and cultural implications of mitigation solutions.more » « less
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The field of oceanography is transitioning from data-poor to data-rich, thanks in part to increased deployment ofin-situplatforms and sensors, such as those that instrument the US-funded Ocean Observatories Initiative (OOI). However, generating science-ready data products from these sensors, particularly those making biogeochemical measurements, often requires extensive end-user calibration and validation procedures, which can present a significant barrier. Openly available community-developed and -vetted Best Practices contribute to overcoming such barriers, but collaboratively developing user-friendly Best Practices can be challenging. Here we describe the process undertaken by the NSF-funded OOI Biogeochemical Sensor Data Working Group to develop Best Practices for creating science-ready biogeochemical data products from OOI data, culminating in the publication of the GOOS-endorsed OOI Biogeochemical Sensor Data Best Practices and User Guide. For Best Practices related to ocean observatories, engaging observatory staff is crucial, but having a “user-defined” process ensures the final product addresses user needs. Our process prioritized bringing together a diverse team and creating an inclusive environment where all participants could effectively contribute. Incorporating the perspectives of a wide range of experts and prospective end users through an iterative review process that included “Beta Testers’’ enabled us to produce a final product that combines technical information with a user-friendly structure that illustrates data analysis pipelines via flowcharts and worked examples accompanied by pseudo-code. Our process and its impact on improving the accessibility and utility of the end product provides a roadmap for other groups undertaking similar community-driven activities to develop and disseminate new Ocean Best Practices.more » « less
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Abstract. Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere in a changing climate is critical to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe and synthesize datasets and methodologies to quantify the five major components of the global carbon budget and their uncertainties. Fossil CO2 emissions (EFOS) are based on energy statistics and cement production data, while emissions from land-use change (ELUC) are based on land-use and land-use change data and bookkeeping models. Atmospheric CO2 concentration is measured directly, and its growth rate (GATM) is computed from the annual changes in concentration. The global net uptake of CO2 by the ocean (SOCEAN, called the ocean sink) is estimated with global ocean biogeochemistry models and observation-based fCO2 products (fCO2 is the fugacity of CO2). The global net uptake of CO2 by the land (SLAND, called the land sink) is estimated with dynamic global vegetation models. Additional lines of evidence on land and ocean sinks are provided by atmospheric inversions, atmospheric oxygen measurements, and Earth system models. The sum of all sources and sinks results in the carbon budget imbalance (BIM), a measure of imperfect data and incomplete understanding of the contemporary carbon cycle. All uncertainties are reported as ±1σ. For the year 2023, EFOS increased by 1.3 % relative to 2022, with fossil emissions at 10.1 ± 0.5 GtC yr−1 (10.3 ± 0.5 GtC yr−1 when the cement carbonation sink is not included), and ELUC was 1.0 ± 0.7 GtC yr−1, for a total anthropogenic CO2 emission (including the cement carbonation sink) of 11.1 ± 0.9 GtC yr−1 (40.6 ± 3.2 GtCO2 yr−1). Also, for 2023, GATM was 5.9 ± 0.2 GtC yr−1 (2.79 ± 0.1 ppm yr−1; ppm denotes parts per million), SOCEAN was 2.9 ± 0.4 GtC yr−1, and SLAND was 2.3 ± 1.0 GtC yr−1, with a near-zero BIM (−0.02 GtC yr−1). The global atmospheric CO2 concentration averaged over 2023 reached 419.31 ± 0.1 ppm. Preliminary data for 2024 suggest an increase in EFOS relative to 2023 of +0.8 % (−0.2 % to 1.7 %) globally and an atmospheric CO2 concentration increase by 2.87 ppm, reaching 422.45 ppm, 52 % above the pre-industrial level (around 278 ppm in 1750). Overall, the mean of and trend in the components of the global carbon budget are consistently estimated over the period 1959–2023, with a near-zero overall budget imbalance, although discrepancies of up to around 1 GtC yr−1 persist for the representation of annual to semi-decadal variability in CO2 fluxes. Comparison of estimates from multiple approaches and observations shows the following: (1) a persistent large uncertainty in the estimate of land-use change emissions, (2) low agreement between the different methods on the magnitude of the land CO2 flux in the northern extra-tropics, and (3) a discrepancy between the different methods on the mean ocean sink. This living-data update documents changes in methods and datasets applied to this most recent global carbon budget as well as evolving community understanding of the global carbon cycle. The data presented in this work are available at https://doi.org/10.18160/GCP-2024 (Friedlingstein et al., 2024).more » « lessFree, publicly-accessible full text available March 14, 2026
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Abstract. Accurate assessment of anthropogenic carbon dioxide (CO2) emissions andtheir redistribution among the atmosphere, ocean, and terrestrial biospherein a changing climate is critical to better understand the global carboncycle, support the development of climate policies, and project futureclimate change. Here we describe and synthesize data sets and methodologies toquantify the five major components of the global carbon budget and theiruncertainties. Fossil CO2 emissions (EFOS) are based on energystatistics and cement production data, while emissions from land-use change(ELUC), mainly deforestation, are based on land use and land-use changedata and bookkeeping models. Atmospheric CO2 concentration is measureddirectly, and its growth rate (GATM) is computed from the annualchanges in concentration. The ocean CO2 sink (SOCEAN) is estimatedwith global ocean biogeochemistry models and observation-baseddata products. The terrestrial CO2 sink (SLAND) is estimated withdynamic global vegetation models. The resulting carbon budget imbalance(BIM), the difference between the estimated total emissions and theestimated changes in the atmosphere, ocean, and terrestrial biosphere, is ameasure of imperfect data and understanding of the contemporary carboncycle. All uncertainties are reported as ±1σ. For the year 2021, EFOS increased by 5.1 % relative to 2020, withfossil emissions at 10.1 ± 0.5 GtC yr−1 (9.9 ± 0.5 GtC yr−1 when the cement carbonation sink is included), and ELUC was 1.1 ± 0.7 GtC yr−1, for a total anthropogenic CO2 emission(including the cement carbonation sink) of 10.9 ± 0.8 GtC yr−1(40.0 ± 2.9 GtCO2). Also, for 2021, GATM was 5.2 ± 0.2 GtC yr−1 (2.5 ± 0.1 ppm yr−1), SOCEAN was 2.9 ± 0.4 GtC yr−1, and SLAND was 3.5 ± 0.9 GtC yr−1, with aBIM of −0.6 GtC yr−1 (i.e. the total estimated sources were too low orsinks were too high). The global atmospheric CO2 concentration averaged over2021 reached 414.71 ± 0.1 ppm. Preliminary data for 2022 suggest anincrease in EFOS relative to 2021 of +1.0 % (0.1 % to 1.9 %)globally and atmospheric CO2 concentration reaching 417.2 ppm, morethan 50 % above pre-industrial levels (around 278 ppm). Overall, the meanand trend in the components of the global carbon budget are consistentlyestimated over the period 1959–2021, but discrepancies of up to 1 GtC yr−1 persist for the representation of annual to semi-decadalvariability in CO2 fluxes. Comparison of estimates from multipleapproaches and observations shows (1) a persistent large uncertainty in theestimate of land-use change emissions, (2) a low agreement between thedifferent methods on the magnitude of the land CO2 flux in the northernextratropics, and (3) a discrepancy between the different methods on thestrength of the ocean sink over the last decade. This living data updatedocuments changes in the methods and data sets used in this new globalcarbon budget and the progress in understanding of the global carbon cyclecompared with previous publications of this data set. The data presented inthis work are available at https://doi.org/10.18160/GCP-2022 (Friedlingstein et al., 2022b).more » « less
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This dataset consists of the Surface Ocean CO2 Atlas Version 2022 (SOCATv2022) data product files. The ocean absorbs one quarter of the global CO2 emissions from human activity. The community-led Surface Ocean CO2 Atlas (www.socat.info) is key for the quantification of ocean CO2 uptake and its variation, now and in the future. SOCAT version 2022 has quality-controlled in situ surface ocean fCO2 (fugacity of CO2) measurements on ships, moorings, autonomous and drifting surface platforms for the global oceans and coastal seas from 1957 to 2021. The main synthesis and gridded products contain 33.7 million fCO2 values with an estimated accuracy of better than 5 μatm. A further 6.4 million fCO2 sensor data with an estimated accuracy of 5 to 10 μatm are separately available. During quality control, marine scientists assign a flag to each data set, as well as WOCE flags of 2 (good), 3 (questionable) or 4 (bad) to individual fCO2 values. Data sets are assigned flags of A and B for an estimated accuracy of better than 2 μatm, flags of C and D for an accuracy of better than 5 μatm and a flag of E for an accuracy of better than 10 μatm. Bakker et al. (2016) describe the quality control criteria used in SOCAT versions 3 to 2022. Quality control comments for individual data sets can be accessed via the SOCAT Data Set Viewer (www.socat.info). All data sets, where data quality has been deemed acceptable, have been made public. The main SOCAT synthesis files and the gridded products contain all data sets with an estimated accuracy of better than 5 µatm (data set flags of A to D) and fCO2 values with a WOCE flag of 2. Access to data sets with an estimated accuracy of 5 to 10 (flag of E) and fCO2 values with flags of 3 and 4 is via additional data products and the Data Set Viewer (Table 8 in Bakker et al., 2016). SOCAT publishes a global gridded product with a 1° longitude by 1° latitude resolution. A second product with a higher resolution of 0.25° longitude by 0.25° latitude is available for the coastal seas. The gridded products contain all data sets with an estimated accuracy of better than 5 µatm (data set flags of A to D) and fCO2 values with a WOCE flag of 2. Gridded products are available monthly, per year and per decade. Two powerful, interactive, online viewers, the Data Set Viewer and the Gridded Data Viewer (www.socat.info), enable investigation of the SOCAT synthesis and gridded data products. SOCAT data products can be downloaded. Matlab code is available for reading these files. Ocean Data View also provides access to the SOCAT data products (www.socat.info). SOCAT data products are discoverable, accessible and citable. The SOCAT Data Use Statement (www.socat.info) asks users to generously acknowledge the contribution of SOCAT scientists by invitation to co-authorship, especially for data providers in regional studies, and/or reference to relevant scientific articles. The SOCAT website (www.socat.info) provides a single access point for online viewers, downloadable data sets, the Data Use Statement, a list of contributors and an overview of scientific publications on and using SOCAT. Automation of data upload and initial data checks allows annual releases of SOCAT from version 4 onwards. SOCAT is used for quantification of ocean CO2 uptake and ocean acidification and for evaluation of climate models and sensor data. SOCAT products inform the annual Global Carbon Budget since 2013. The annual SOCAT releases by the SOCAT scientific community are a Voluntary Commitment for United Nations Sustainable Development Goal 14.3 (Reduce Ocean Acidification) (#OceanAction20464). More broadly the SOCAT releases contribute to UN SDG 13 (Climate Action) and SDG 14 (Life Below Water), and to the UN Decade of Ocean Science for Sustainable Development. Hundreds of peer-reviewed scientific publications and high-impact reports cite SOCAT. The SOCAT community-led synthesis product is a key step in the value chain based on in situ inorganic carbon measurements of the oceans, which provides policy makers with critical information on ocean CO2 uptake in climate negotiations. The need for accurate knowledge of global ocean CO2 uptake and its (future) variation makes sustained funding of in situ surface ocean CO2 observations imperative.more » « less
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Abstract. Accurate assessment of anthropogenic carbon dioxide(CO2) emissions and their redistribution among the atmosphere,ocean, and terrestrial biosphere – the “global carbon budget” – isimportant to better understand the global carbon cycle, support thedevelopment of climate policies, and project future climate change. Here wedescribe data sets and methodology to quantify the five major components ofthe global carbon budget and their uncertainties. Fossil CO2emissions (EFF) are based on energy statistics and cementproduction data, while emissions from land use and land-use change (ELUC),mainly deforestation, are based on land use and land-use change data andbookkeeping models. Atmospheric CO2 concentration is measureddirectly and its growth rate (GATM) is computed from the annualchanges in concentration. The ocean CO2 sink (SOCEAN)and terrestrial CO2 sink (SLAND) are estimated withglobal process models constrained by observations. The resulting carbonbudget imbalance (BIM), the difference between the estimatedtotal emissions and the estimated changes in the atmosphere, ocean, andterrestrial biosphere, is a measure of imperfect data and understanding ofthe contemporary carbon cycle. All uncertainties are reported as ±1σ. For the last decade available (2008–2017), EFF was9.4±0.5 GtC yr−1, ELUC 1.5±0.7 GtC yr−1, GATM 4.7±0.02 GtC yr−1,SOCEAN 2.4±0.5 GtC yr−1, and SLAND 3.2±0.8 GtC yr−1, with a budget imbalance BIM of0.5 GtC yr−1 indicating overestimated emissions and/or underestimatedsinks. For the year 2017 alone, the growth in EFF was about 1.6 %and emissions increased to 9.9±0.5 GtC yr−1. Also for 2017,ELUC was 1.4±0.7 GtC yr−1, GATM was 4.6±0.2 GtC yr−1, SOCEAN was 2.5±0.5 GtC yr−1, and SLAND was 3.8±0.8 GtC yr−1,with a BIM of 0.3 GtC. The global atmosphericCO2 concentration reached 405.0±0.1 ppm averaged over 2017.For 2018, preliminary data for the first 6–9 months indicate a renewedgrowth in EFF of +2.7 % (range of 1.8 % to 3.7 %) basedon national emission projections for China, the US, the EU, and India andprojections of gross domestic product corrected for recent changes in thecarbon intensity of the economy for the rest of the world. The analysispresented here shows that the mean and trend in the five components of theglobal carbon budget are consistently estimated over the period of 1959–2017,but discrepancies of up to 1 GtC yr−1 persist for the representationof semi-decadal variability in CO2 fluxes. A detailed comparisonamong individual estimates and the introduction of a broad range ofobservations show (1) no consensus in the mean and trend in land-use changeemissions, (2) a persistent low agreement among the different methods onthe magnitude of the land CO2 flux in the northern extra-tropics,and (3) an apparent underestimation of the CO2 variability by oceanmodels, originating outside the tropics. This living data update documentschanges in the methods and data sets used in this new global carbon budgetand the progress in understanding the global carbon cycle compared withprevious publications of this data set (Le Quéré et al., 2018, 2016,2015a, b, 2014, 2013). All results presented here can be downloaded fromhttps://doi.org/10.18160/GCP-2018.more » « less
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Abstract. The Surface Ocean CO2 Atlas (SOCAT) is a synthesis of quality-controlled fCO2 (fugacity of carbon dioxide) values for the global surface oceans and coastal seas with regular updates. Version 3 of SOCAT has 14.7 million fCO2 values from 3646 data sets covering the years 1957 to 2014. This latest version has an additional 4.6 million fCO2 values relative to version 2 and extends the record from 2011 to 2014. Version 3 also significantly increases the data availability for 2005 to 2013. SOCAT has an average of approximately 1.2 million surface water fCO2 values per year for the years 2006 to 2012. Quality and documentation of the data has improved. A new feature is the data set quality control (QC) flag of E for data from alternative sensors and platforms. The accuracy of surface water fCO2 has been defined for all data set QC flags. Automated range checking has been carried out for all data sets during their upload into SOCAT. The upgrade of the interactive Data Set Viewer (previously known as the Cruise Data Viewer) allows better interrogation of the SOCAT data collection and rapid creation of high-quality figures for scientific presentations. Automated data upload has been launched for version 4 and will enable more frequent SOCAT releases in the future. High-profile scientific applications of SOCAT include quantification of the ocean sink for atmospheric carbon dioxide and its long-term variation, detection of ocean acidification, as well as evaluation of coupled-climate and ocean-only biogeochemical models. Users of SOCAT data products are urged to acknowledge the contribution of data providers, as stated in the SOCAT Fair Data Use Statement. This ESSD (Earth System Science Data) "living data" publication documents the methods and data sets used for the assembly of this new version of the SOCAT data collection and compares these with those used for earlier versions of the data collection (Pfeil et al., 2013; Sabine et al., 2013; Bakker et al., 2014). Individual data set files, included in the synthesis product, can be downloaded here: doi:10.1594/PANGAEA.849770. The gridded products are available here: doi:10.3334/CDIAC/OTG.SOCAT_V3_GRID.more » « less
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